cis-Dichloridobis(1,10-phenanthroline)chromium(III) chloride
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چکیده
منابع مشابه
Tripyridinium cis-tetrachloridodioxidomolybdate(VI) chloride
In the title compound, (C(5)H(6)N)(3)[MoCl(4)O(2)]Cl, the pyridinium cations are N-H⋯Cl hydrogen bonded to the anionic [MoCl(4)O(2)](2-) complexes and to the two crystallographically independent chloride anions (located on C2 axes). The Mo(6+) centre adopts a highly distorted octa-hedral geometry, being surrounded by four chloride and two terminal oxide groups. The oxide ligands are mutually cis.
متن کاملcis-Dichloridobis(1,10-phenanthroline)chromium(III) chloride
In the title complex, [CrCl(2)(C(12)H(8)N(2))(2)]Cl, the Cr(III) ion is situated on a twofold rotation axis and displays a slightly distorted octa-hedral CrCl(2)N(4) coordination geometry. The Cr environment is composed of a cis arrangement of two 1,10-phenanthroline and two chloride ligands. The chloride counter-anion exhibits half-occupation and is equally disordered over two positions.
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Of the bisurea compounds linked through trans- and cis-benzanilide spacers, the cis-amide derivatives were found to be effective in chloride transport, using which a stimuli-responsive mobile carrier was devised.
متن کاملcis,cis,cis-(Acetato-κ2 O,O′)bis[1,2-bis(diphenylphosphanyl)ethane-κ2 P,P′]ruthenium(II) 0.75-trifluoromethanesulfonate 0.25-chloride
In the title Ru(II) carboxyl-ate compound, [Ru(C2H3O2)(C26H24P2)2](CF3O3S)0.75Cl0.25, the distorted tris-bidentate octa-hedral stereochemistry about the Ru(II) atom in the complex cation comprises four P-atom donors from two 1,2-bis-(diphenyl-phosphan-yl)ethane ligands [Ru-P = 2.2881 (13)-2.3791 (13) Å] and two O-atom donors from the acetate ligand [Ru-O = 2.191 (3) and 2.202 (3) Å]. The disord...
متن کاملThe isomerization equilibrium between cis and trans chloride ruthenium olefin metathesis catalysts from quantum mechanics calculations.
The cis-trans chloride isomerization of a ruthenium olefin metathesis catalyst is studied using quantum mechanics (B3LYP DFT), including the Poisson-Boltzmann (PBF) continuum approximation. The predicted geometries agree with experiment. The energies in methylene chloride, lead to DeltaG = -0.70 kcal/mol and a cis:trans ratio of 76:24, quite close to the experimental value of DeltaG = -0.78 kca...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536810053845